07/01/2014
Types of ceramic materials
Crystalline ceramics
Crystalline ceramic materials are not amendable to a great range of processing. Methods for dealing with them tend to fall into one of two categories - either make the ceramic in the desired shape, by reaction in situ, or by "forming" powders into the desired shape, and then sintering to form a solid body. Ceramic forming techniques include shaping by hand (sometimes including a rotation process called "throwing"), slip casting, tape casting (used for making very thin ceramic capacitors, etc.), injection moulding, dry pressing, and other variations. (See also Ceramic forming techniques. Details of these processes are described in the two books listed below.) A few methods use a hybrid between the two approaches of butohing and pukiying.
Non-crystalline ceramics
Non-crystalline ceramics, being glasses, tend to be formed from melts. The glass is shaped when either fully molten, by casting, or when in a state of toffee-like viscosity, by methods such as blowing to a mold. If later heat-treatments cause this glass to become partly crystalline, the resulting material is known as a glass-ceramic.
Properties of ceramics
The physical properties of any ceramic substance are a direct result of its crystalline structure and chemical composition. Solid state chemistry reveals the fundamental connection between microstructure and properties such as localized density variations, grain size distribution, type of porosity and second-phase content, which can all be correlated with ceramic properties such as mechanical strength σ by the Hall-Petch equation, hardness, toughness, dielectric constant, and the optical properties exhibited by transparent materials.
Physical properties of chemical compounds which provide evidence of chemical composition include odor, color, volume, density (mass / volume), melting point, boiling point, heat capacity, physical form at room temperature (solid, liquid or gas), hardness, porosity, and index of refraction.
Ceramography is the art and science of preparation, examination and evaluation of ceramic microstructures. Evaluation and characterization of ceramic microstructures is often implemented on similar spatial scales to that used commonly in the emerging field of nanotechnology: from tens of angstroms (A) to tens of micrometers (µm). This is typically somewhere between the minimum wavelength of visible light and the resolution limit of the naked eye.
The microstructure includes most grains, secondary phases, grain boundaries, pores, micro-cracks, structural defects and hardness microindentions. Most bulk mechanical, optical, thermal, electrical and magnetic properties are significantly affected by the observed microstructure. The fabrication method and process conditions are generally indicated by the microstructure. The root cause of many ceramic failures is evident in the cleaved and polished microstructure. Physical properties which constitute the field of materials science and engineering include the following:
Mechanical properties[edit]
Cutting disks made of SiC
The Porsche Carrera GT's carbon-ceramic (silicon carbide) disc brake
Mechanical properties are important in structural and building materials as well as textile fabrics. They include the many properties used to describe the strength of materials such as: elasticity / plasticity, tensile strength, compressive strength, shear strength, fracture toughness & ductility (low inbrittle materials), and indentation hardness.
Fracture mechanics is the field of mechanics concerned with the study of the formation and subsequent propagation of microcracks in materials. It uses methods of analytical solid mechanics to calculate the thermodynamic driving force on a crack and the methods of experimental solid mechanics to characterize the material's resistance to fracture and catastrophic failure.
In modern materials science, fracture mechanics is an important tool in improving the mechanical performance of materials and components. It applies the physics of stress and strain, in particular the theories of elasticity and plasticity, to the microscopic crystallographic defects found in real materials in order to predict the macroscopic mechanical failure of bodies. Fractography is widely used with fracture mechanics to understand the causes of failures and also verify the theoretical failure predictions with real life failures.
Thus, since cracks and other microstructural defects can lower the strength of a structure beyond that which might be predicted by the theory of crystalline objects, a different property of the material—above and beyond conventional strength—is needed to describe the fracture resistance of engineering materials. This is the reason for the need for fracture mechanics: the evaluation of the strength of flawed structures.
In this context, Fracture toughness is a property which describes the ability of a material containing a crack to resist fracture, and is one of the most important properties of any material for virtually all design applications. Fracture toughness is a quantitative way of expressing a material's resistance tobrittle fracture when a crack is present. If a material has a large value of fracture toughness it will probably undergo ductile fracture. Brittle fracture is very characteristic of materials with a low fracture toughness value. Fracture mechanics, which leads to the concept of fracture toughness, was largely based on the work of A. A. Griffith who, amongst other things, studied the behaviour of cracks in brittle materials. This describes "ceramics are strong in compression and weak in tension"
Ceramic materials are usually ionic or covalent bonded materials, and can be crystalline or amorphous. A material held together by either type of bond will tend to fracture before any plastic deformation takes place, which results in poor toughness in these materials. Additionally, because these materials tend to be porous, the pores and other microscopic imperfections act as stress concentrators, decreasing the toughness further, and reducing the tensile strength. These combine to give catastrophic failures, as opposed to the normally much more gentle failure modes of metals.
These materials do show plastic deformation. However, due to the rigid structure of the crystalline materials, there are very few available slip systems for dislocations to move, and so they deform very slowly. With the non-crystalline (glassy) materials, viscous flow is the dominant source of plastic deformation, and is also very slow. It is therefore neglected in many applications of ceramic materials.
To overcome the brittle behaviour, ceramic material development has introduced the class of ceramic matrix composite materials, in which ceramic fibers are embedded and with specific coatings are forming fiber bridges across any crack. This mechanism substantially increases the fracture toughness of such ceramics. The ceramic disc brakes are, for example using a ceramic matrix composite material manufactured with a specific process.
